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China's earliest tinned iron armor found in Zhejiang: 1,700-year-old anti-rust tech revealed_我的网站

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A number of tinned iron armor plates excavated from the Jizhong site Photo: Courtesy of the Shaoxing Institute of Cultural Relics and Archaeology
    A number of tinned iron armor plates excavated from the Jizhong site Photo: Courtesy of the Shaoxing Institute of Cultural Relics and ArchaeologyArchaeologists at the Jizhong ruins site in Shaoxing, East China's Zhejiang Province, recently unearthed a large number of tinned iron armor plates and semi-finished pieces dating to the Wu period of the Three Kingdoms (222-280), according to the Shaoxing Institute of Cultural Relics and Archaeology. These discoveries represent the earliest known tinned iron artifacts in China to date, as well as the earliest tinned iron production remains found anywhere in the world, proving that an organized, systematic craft industry for tin-plated ironwork existed at that time.
While China has a long history of making tinned bronze and tinware, there has long been a lack of reliable historical records or physical evidence to prove early local production of tinned iron artifacts. The newly discovered armor plates can fill this gap, demonstrating that, by no later than the Wu period, local craftspeople in Zhejiang Province had mastered the art of tin-plating iron surfaces. This reflects the region's advanced metallurgical skills at that time, Ge Shuaikun, a researcher at the Shaoxing Institute of Cultural Relics and Archaeology, told the Global Times on Tuesday.
Over the last three years, archaeologists working at the Jizhong ruins site have excavated hundreds of tinned iron armor plates from ancient wells and ash pits. A preliminary investigation confirmed that the surfaces of these plates contain high levels of tin. Subsequent laboratory analyses were conducted in collaboration with the Shaoxing's institute and the Institute for Cultural Heritage and History of Science & Technology at the University of Science and Technology Beijing with methods such as Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM-EDS), X-ray Diffraction (XRD), and Micro-CT to deeply examine the samples' materials, structures, and technological traces.
Photo: Courtesy of the Shaoxing Institute of Cultural Relics and Archaeology
    Photo: Courtesy of the Shaoxing Institute of Cultural Relics and ArchaeologyAccording to Ge, tin is a non-toxic metal with a low melting point, excellent corrosion resistance, and a silvery sheen. Tin plating effectively prevents rust, making iron armor far more durable and indeed, even after being buried for 1,700 years, many of these tinned plates retain their silvery metallic shine.
Research shows that the craftspeople immersed iron armor plates in molten tin, thus ensuring complete coverage of the surface with a continuous tinned layer. This coating isolated the iron from exposure to air and moisture, dramatically boosting corrosion resistance. Many of the excavated tinned armor pieces still show a clear, bright silver-white finish.
One major reason for tin-plating the armor was to prevent rust. At the same time, the silvery white shine of tinned iron offered a more striking, beautiful appearance, standing out from the typical dark iron armor of the era. This visual distinction may have marked these pieces as a higher-grade military asset, according to an article from the University of Science and Technology Beijing's official website.
The article said that in earlier eras, from the pre-Qin to Han dynasties, tin was widely used as a surface coating on bronzeware and ceramics. Researchers believe the tin-plating of iron armor discovered at the Jizhong ruins site during the Wu period of Three Kingdoms built upon this local tin-coating tradition, representing an adaptation of those techniques across different materials. The process likely benefited from technological exchange among various specialized workshops at the site, including those making bronze castings, iron weapons, and other metallurgical products.
。    8月24日消息,美国加拿大贸易摩擦持续发酵,在首轮关税落地、双边谈判破裂之后,美国再度抛出重磅威胁。    特朗普业已官宣,计划自2027年1月1日起,对加拿大全部大小汽车、卡车、整车零部件以及钢铁征收50%关税,上述品类并未纳入此前的征税清单。     以下为特朗普分享的原文:     加拿大多年来一直在占美国的便宜,加拿大对美国农民以及农产品征收高得离谱的关税,让这些优秀的美国爱国者举步维艰,也造成两国之间长期存在600亿美元的贸易逆差,这种局面无法持续,这种情况到此为止!     2027年1月1日起,针对全部大小汽车、卡车、汽车零部件以及钢铁的关税,将上调至50%。    如果在美国本土生产,则享受零关税待遇,加拿大将不再被视作美国的一个州来对待!     在贸易以及其他诸多方面,加拿大都属于最难打交道的国家之一。

B |     他们总觉得自己理应享受优待,但现实是:我们并不依赖加拿大,而是加拿大离不开我们!加拿大95%的贸易业务都是和美国开展的,情况完全反过来了!     

    据了解,本轮争端根源来自农产品市场准入矛盾,美方指责加拿大乳制品、酒类相关规则设置贸易壁垒,叠加双边约600亿美元贸易逆差,以此作为施压借口。     7月美国宣布对加拿大酒水、建材等商品加征50%关税,原定8月19日生效,后因谈判短暂推迟,最终8月22日正式落地,但并未涉及汽车与钢铁品类。    多轮谈判中双方一度传出妥协信号,但美方追加苛刻条款,谈判彻底破裂,加拿大随即宣布,9月8日起实施对等报复关税。     为进一步逼迫加拿大让步,美国将矛头指向深度绑定的北美汽车供应链,设置4个多月缓冲期,并非即刻执行,既给谈判留出窗口,也减少对本国车企的即时冲击。

C |     北美汽车产业高度一体化,加拿大大量整车与零部件供应美国工厂,一旦50%关税落地,跨境生产成本将大幅抬升,直接冲击区域供应链,推高整车售价

D |     需要指出的是,目前该政策还属于对外宣告,后续仍存在谈判调整的可能性,而加拿大也大概率出台对应反制举措。              

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